Italy's Niccolo Campriani won gold in the Olympic men's 10-metre air rifle on Monday with a score of 206.1 after Serihy Kulish of Ukraine made his final shot poorly, widening what had been a razor-thin gap between the two.
Among India's other two competitors in the qualifiers which ended late on Sunday, Divyansh Singh Panwar ended 25th with a score of 626.8 while Srinjoy Datta shot 616.6 to finish 82nd.
He joins pistol shooter Jitu Rai, rifle shooters Apurvi Chandela and Gagan Narang, who all had sealed berths earlier.
Participating in the continental tournament as guest invitee, the Indians only shot in the MQS section, and hence, their scores were not considered for medals.
A summary of sports events and persons who made news on Saturday
Abhinav Bindra's quest for a second Olympics medal ended in disappointment, as he lost a tense shoot-off in the men's 10 metre Air Rifle event on the third day of competition at the Rio Games on Monday.
Hosts Brazil won their first gold of the Rio 2016 Summer Games after Rafaela Silva won the women's-57kg judo event on Monday. Another country to open their 'gold account' was Croatia, thanks to trap shooter Josip Glasnovic's superb effort in the shoot-out.